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Needless Risk: Oil Refineries and Hazard Reduction

08/04/2005

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Executive Summary

Environment America is the new home of U.S. PIRG's environmental work.

Across the country, petroleum refineries, chemical plants and other industrial facilities use and store large amounts of hazardous chemicals that could be released in the event of an accident or terrorist attack. Such releases could endanger thousands or even millions of people who live in communities in close proximity to these facilities. According to the Environmental Protection Agency (EPA), 106 facilities would each endanger at least one million people in the event of a worst-case chemical release. Another 3,000 facilities would endanger at least 10,000 people. Nearly 5,000 facilities store more than 100,000 pounds of at least one EPA classified “extremely hazardous substance.”

Many of these facilities, however, present an unnecessary risk to their surrounding communities. Industries often have multiple options for carrying out similar processes, and some of these options are inherently safer than others. Facilities that use fewer or smaller quantities of hazardous chemicals, or even make changes to storage pressure or other processes, can eliminate the possibility of on-site chemical accidents and make themselves less appealing terrorist targets.

Petroleum refineries stand as a stark example of the needless risk posed by such facilities in the event of an attack or accident as well as the opportunity to mitigate this risk by using safer alternatives to toxic chemicals.

Many petroleum refineries use hydrofluoric acid in their processing, which poses a great public safety risk both because of its extreme toxicity to humans as well as its propensity to form a toxic aerosol cloud when released. A catastrophic event at one of these facilities could cause a potentially lethal release of hydrofluoric acid, forming a stable aerosol cloud above the facility and surrounding neighborhoods. Exposure to hydrofluoric acid results in devastating burns, and pain associated with the exposure may be delayed for up to 24 hours. If the burn is not addressed, tissue destruction may continue for days. Inhalation of fumes can cause symptoms ranging from severe throat irritation to pulmonary edema.

To estimate the number of Americans at needless risk of exposure to hydrofluoric acid in the event of a catastrophic accident or terrorist attack at a petroleum refinery, we examined the Risk Management Plans submitted by oil refineries to EPA. These plans estimate how far a chemical could travel off-site in the event of a release and report the number of people living within the “vulnerability zone,” the area potentially affected by the release. Based on this data, we found that petroleum refineries using hydrofluoric acid endanger millions of people.

Specifically:
• Of the 148 petroleum refineries in the United States, 50 use hydrofluoric acid in their processing or store it on-site. The remainder use safer alternatives, such as sulfuric acid.

• These 50 refineries, using and storing 10.6 million pounds of hydrofluoric acid, endanger more than 17 million people living in surrounding communities in 20 different states.

• With 12 refineries using hydrofluoric acid, Texas has more than any state. Louisiana has five oil refineries that currently use hydrofluoric acid, and Montana has four.

• Refineries using hydrofluoric acid in Pennsylvania endanger more than 4.4 million people residing in their vulnerability zones, according to conservative estimates. Refineries using hydrofluoric acid in both Illinois and New Jersey endanger more than 3.1 million people living within the vulnerability zones.

• Seven petroleum refineries using hydrofluoric acid reported toxic release “worst-case” scenarios in which more than one million people could be affected. Furthermore, 15 refineries could place more than 500,000 people in harm’s way, and 28 refineries could endanger more than 100,000 people in the event of a worst-case hydrofluoric acid release.

• The companies operating refineries using hydrofluoric acid with the most people residing in their vulnerability zones include Sunoco, Valero Energy Corporation, Marathon Ashland Petroleum, ConocoPhillips, CITGO, and ExxonMobil, each endangering at least two million people in total.

• Many companies owning refineries using hydrofluoric acid also operate refineries without that technology. ConocoPhillips,ExxonMobil, Valero Energy Corporation, and Marathon Ashland, for example, own refineries using hydrofluoric acid as well
as refineries that use other technologies.

Fortunately, hydrofluoric acid is not the only material oil refineries can use in their refining processes. Many other refineries already use sulfuric acid, a safer alternative, in the alkylation process. This cost-effective and widely-used alternative diminishes the appeal of refineries as a terrorist target and mitigates the public health and safety consequences of an accident. In addition, a new technology, solid acid catalysts, will soon be available for widespread commercial use, offering an even safer option than the use of sulfuric acid.

Petroleum refineries are but one example of the facilities that pose an immediate risk to public health in the event of a terrorist attack or chemical accident. Refineries also are not the only example of facilities that could make cost-effective changes to manufacturing processes to reduce or eliminate the use of hazardous chemicals.

Unfortunately, most industrial facilities have not responded to the increased awareness of terrorism by switching to inherently safer technologies. Instead, industry organizations such as the American Chemistry Council, the American Petroleum Institute, and the National Petrochemical and Refiners Association have emphasized increasing physical security at facilities. Hiring more guards, building higher fences, and placing more lights may all be part of a strong security plan, but this does not actually reduce the threat to the community. Switching chemicals and processes to something less volatile not only reduces the chemical hazard to the community, but also reduces the need for costly add-on security measures and the attractiveness of the facility as a target for attack.